Qualitative analysis of fluid dynamics and heat transfer characteristics in porous structures towards aqueous phase reforming hydrogen production

Porous structure is commonly used as a catalytic support in the field of fixed-bed reactor for hydrogen production from methanol aqueous phase reforming. The fluid dynamics and heat transfer characteristics of the fluid in a specific porous structure are considered profound influences for catalytic reactions. This study presented a qualitative investigation on the flow and heat transfer characteristics of fluids in variable porous structures. Specifically, the discrete average interpolation method was employed to obtain the value of a continuous structure. From the results, using the area-average temperature equation was 11% (±1.5%) larger and precise than that from the previous work using traditional hydrodynamic equation. The proposed variable porous structure could not only increase the turbulence intensity of the fluid which could further enhance reaction mass transfer but also enhance the convective heat transfer of the fluidic reactants. Some of these findings could inspire the reactor design for improving catalytic efficiency of hydrogen production.     

Enhanced photo-electrochemical activity of ZnO/Cu2S nanotube arrays photocathodes

ZnO/Cu₂S nanotube arrays are fabricated firstly by a facile and capping-agent-free method, and the photo-electrochemical performance has been studied systematically. The results show that ZnO/Cu₂S nanotube arrays achieve enhanced photo-electrochemical water splitting performance and the photocurrent densities of ZnO/Cu₂S are 7.9 times than that of ZnO at 0 V versus Ag/AgCl. The performance of the ZnO/Cu₂S nanotube arrays can be adjusted by changing the amount of Cu₂S microcrystals. The results confirm that the enhanced photo-electrochemical performance of ZnO/Cu₂S is due to the significantly improved visible light absorption, effective separation of photo-induced carriers due to the well band energy match and the formed p-n junction between ZnO and Cu₂S.     

铜矿床一般工业指标研究

针对2002年铜地质勘查规范中一般工业指标存在的问题,基于大量实际生产数据,对铜矿床实际采用的边界品位指标、最低工业品位、矿床平均品位、最小可采厚度、夹石剔除厚度、开采技术条件等进行研究,论证了铜矿床的一般工业指标,并首次明确了铜矿床工业指标的适用条件,解决了铜矿床一般工业指标体系应用不一致和指标区间取值主观性的问题。     

高压下CL-20拉曼光谱和红外光谱相变研究

为了更好地认识和了解CL-20晶体结构演变规律和相变行为,利用金刚石对顶砧超高压实验技术,在0~50GPa下,研究了高压下ε-CL-20的原位拉曼光谱和红外光谱。结果表明,CL-20晶体在整个加压过程中存在两个相变,第一个相变发生在4.2~7.5GPa,认为是ε相到对称性更低的γ相转变,相变产生的原因是在压强的作用下,笼环外的硝基方向发生改变,电子云密度重置导致的分子构型转变;第二个相变发生在14.2~18.9GPa,属于γ相到ζ相的晶体结构转变;卸压后,拉曼和红外光谱恢复常压状态,表明CL-20晶体在研究压强范围内的相变过程是可逆的。     

Evaluating the profile of myofibrillar proteins and its relationship with tenderness among five styles of dry-cured hams

In order to investigate the relationship between profile of myofibrillar proteins and tenderness among 2 kinds of Chinese hams (Jinhua and Xuanwei) and 3 kinds of European hams (Iberian, Serrano and Parma), shear force, myofibril fragmentation index (MFI), SDS-PAGE, carbonyls content and Raman spectroscopy were investigated. The shear force and salt content of Chinese hams were significantly higher than that of European hams, while moisture content was lower than that of European hams (p < 0.05). MFI values and SDS-PAGE profile revealed that the degradation of myofibrillar proteins in Chinese hams was lower than in European hams. In addition, Chinese hams showed significantly higher carbonyls content and β-sheet content compared with European hams, indicated that proteins aggregation intensively inhibited the degradation of myofibrillar proteins in Chinese hams. These results indicated that the higher shear force in Chinese style hams could be attributed to the lower moisture content and limited proteolysis.     

Lead-free sodium niobate nanowires with strong piezo-catalysis for dye wastewater degradation

In this work, the hydrothermally-synthesized sodium niobate nanowires were used to decompose Rhodamine B dye solution through the piezo-catalytic effect. With the sodium niobate catalyst, a high piezo-catalytic degradation ratio of ～80% was achieved under the excitation of vibration for the Rhodamine B dye solution (～5?mg/l). These active species in the catalytic process, hydroxyl radicals and superoxide radicals with the strong oxidation ability, were also observed, which confirmed the key role of piezoelectric effect for piezo-catalysis. The piezo-catalysis of sodium niobate nanowires provides a high-efficiency and reusable tool in application in depredating the dye wastewater.     

QKD系统中基于EA电路的诱骗态实现

使用诱骗态量子秘钥方案可以解决因光子数分离攻击而导致的安全漏洞,保证了长距离量子通信的安全。本文介绍了量子通信的相关原理,通过对电吸收调制电路和激光器驱动电路的设计,精确控制产生了1550 nm波段的窄脉冲,经过内部调制成功制备诱骗态光脉冲,其强度约为信号态光脉冲的三分之一,因激光器的同一性而具有一致的光学特征从而避免了时频窃听,并具有强度可调的优点。     

互联网+产学研合作智能服务平台的生态服务模式

在“互联网+”大环境下，以用户价值为导向、加速供需双方实现技术转移、各取所需为核心的，以产业链整合、加强横向用户关系圈扩展、助力进一步解决产学研信息不对称的，以扩大产学研合作范围、提升产学研合作成效为目标的产学研合作生态服务模式应运而生.基于产学研合作生态服务模式，构建生态服务模型，应用于实践，建设“互联网+产学研合作智能服务平台”，提供多样化的产学研内容、社交和对接生态服务，并取得了显著的成效.